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The concern is timing: taking glutathione while actively drinking may reduce its availability for acetaldehyde detoxification during the peak metabolism phase

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It also exacerbates high blood pressure by damaging blood vessels, contributes to cardiomyopathy by altering heart function, and increases the risk of ischemia by obstructing coronary arteries

doi:10.1016/j.neuroscience.2005.10.014

However, if they differentially stabilize oxidation of free GSH to GSSG, then we would expect to see differences in the level of free GSH measured in the heparinized versus EDTA-treated plasma