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This relationship can be rationalized by the similar chemical mechanism, involving an aromatic nucleophilic attack by the sulfur of glutathione to form a Meisenheimer -complex, which is followed by the release of the common conjugate S-2,4-dinitrophenylglutathione

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10.1046/j.1365-2125.2003.01907.x [DOI] [PMC free article] [PubMed] [Google Scholar] Sterne J., Hernn M., Reeves B., Savovi J., Berkman N., Viswanathan M., et al

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It is also worth noting that A peptides have been shown to significantly decrease the production of melatonin by the pineal gland [58], underscoring the bi-directional nature of these relationships