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It is integral to collagen structure-approximately one-third of the amino-acid content of collagen (the main connective-tissue protein) is glycine

Nat Med (2003) 9(9):11739

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Copper, Collagen, and Controversy: Inside the GHK-Cu Buzz TLDR GHK-Cu is a naturally occurring copper-binding peptide gaining popularity in skin regeneration, wound healing, and inflammation modulation

If there is presence of enzymatic activity and/or spontaneous oxidation in storage, we would expect to observe lower levels of total GSH and free GSH, and elevated levels of GSSG, in the EDTA-treated sample stored at 4 o C compared to the non-deproteinized EDTA-treated plasma stored at 80 o C